WebJun 21, 2011 · Tetracene octaesters, which were prepared by twofold [2+2+2] cocyclization, were isolated as red, orange, and orange-yellow solids for the methyl, ethyl, and propyl ester derivatives, respectively.... Webcrystallochromy effects are derived from the unique crystal-packing patterns. The fluorescence quantum yields in the so-lid state probably depend on the relative positional relation-ship of the nearest neighboring molecules in one column as well as the crystal rigidity. among acenes. Furthermore, the fluorescence quantum

A Theoretical Study of Crystallochromy. Quantum Interference …

WebSynthetically, they are derived from perylene-1,4,5,8-tetracarboxylic acid. The perylenes tend to be quite expensive pigments, but their high levels of fastness properties mean that they are suitable for highly demanding applications. In particular, they offer very high heat stability. Two perinone pigments are used commercially. WebAs demonstrated in a recent model study of several perylene pigments crystallizing in the monoclinic space group P 21/c, the optical properties in the crystalline phase are … is hen leaving 911 for good

Octaalkyl tetracene-1,2,3,4,7,8,9,10-octacarboxylates ... - PubMed

WebAs demonstrated in a recent model study of several perylene pigments crystallizing in the monoclinic space group P2 1 /c, the optical properties in the crystalline phase are determined by the interference between neutral molecular excitations and charge transfer states via electron and hole transfer. WebSep 10, 2009 · Based on the crystal structure determined by x-ray diffraction, density-functional theory (DFT) and Hartree-Fock are used for the calculation of the electronic … WebWhen we searched the literature, we stumbled upon a nice term “crystallochromy,” which defined as the dependence of solid-state color on molecular packing. This term was first brought by a BASF group [ 7 ], who studied a series … is hen is a bird